Catalysis and Electrocatalysis at Nanoparticle Surfaces
Andrzej Wieckowski
University of Illinois
Elena Savinova
Russian Academy of Sciences
DescriptionCatalysis and Electrocatalysis at Nanoparticle Surfaces illustrates the latest developments in electrochemical nanotechnology, heterogeneous catalysis, surface science, and theoretical modeling. It describes the manipulation, characterization, control, and application of nanoparticles for enhanced catalytic activity and selectivity and presents a range of experimental and synthetic strategies for work in nanoscale surface science. Thisis a comprehensive source for physical, surface, and colloid chemists; materials scientists; interfacial chemists and electrochemists; electrochemical engineers; theoretical physicists; chemical engineers; and upper-level undergraduate and graduate students in these disciplines. Table of ContentsTheory of nanoparticle catalysis and electrocatalysis: theory and modelling of catalytic and electrocatalytic reactions - some selected examples; simulations of the reaction kinetics on nm supported catalyst particles; electronic structure and chemisorption properties of supported metal clusters - model calculations. Model systems - from single crystals to nanoparticles: state-of-the-art characterization of single crystal surfaces; single crystal surfaces as model platinum-based fuell cell electrocatalysts; electrochemical nanostructuring of surfaces; adsorption and reaction at supported model catalysts; size-dependent electronic, structural, and catalytic properties of metal clusters supported on ultra-thin oxide films; physical and electrochemical characterization of bimetallic nanoparticle electrodes. Synthetic approaches in nanoparticle catalysis and electrocatalysis: nanomaterials as precursors for electrocatalysts; preparation, characterization, and properties of bimetallic nanoparticles; physicochemical aspects of preparation of carbon supported Nobel metal catalysis. Advanced experimental concepts: NMR investigation of supported metal catalysts; in situ X-ray adsorption spectroscopy investigations of the carbon-supported pt electrocatalysts; STM and infrared spectroscopy in studies of fuel cell model catalysts. Particle size, support, and promotional effects: electrochemical and chemical promotion on metal films and nanoparticles; metal-supported interaction in low temperature fuel cell electrocatalysis; effects of nanoparticle size, structure, and metal-support interactions; promotion, electrochemical promotion and metal-support interactions; support effects on catalytic performance of nanoparticles; abnormal infrared effects of nanometer scale thins film material of platinum group metals and alloys at electrode/electrolyte interfaces; design of electrocatalysts for fuel cells; effect of particle size and support on some catalytic properties of metallic and bimetallic catalysts. Advanced electrocatalytic materials: catalyst nanoparticles on synthetic diamond surfaces; electrocatalysis with electron conduction polymers modified by platinum metal nanoparticles; novel nanostructured material based on transition metal compounds for electrocatalysis.ContributorsContributor Alonso-Vante, Nicolas, Universite de Poitiers, Poitiers, France Contributor Antonucci, P.L., University of Reggio Calabria, Italy Contributor Antonucci, V., Inst for Transformation and Storage of Energy, Messina, ITAL Contributor Arico, A. S., Inst. for Transformation & Storage of Energy, Messina, ITALY Contributor Banerjee, Santanu, University of Southern California, LOS ANGELES, USA Contributor Bonnemann, Helmut, Max-Planck Institute for Kohlenforschung, Germany Contributor Brosda, S., University of Patras, Rio Patras, GREECE Contributor Collins, J. A., Technical University of Munich, Munich, GERMANY Contributor Comninellis, C., Swiss Federal Inst of Technology, Lausanne, SWITZERLAND Contributor Coq, Bernard, ENSCM-CNRS, Montpellier, FRANCE Contributor De Battisti, Achille, Universita di Ferrara, Ferrara, ITALY Contributor Duo, I., Swiss Fed. Inst of Tech, EPFL Contributor Ertl, Gerhard, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Germany Contributor Ferro, Sergio, Universita di Ferrara, Ferrara, ITALY Contributor Figueras, Francois, Institut de Recherche sur la Catalyse, Villeurbanne Cedex,FR Contributor Goodman, D. Wayne, Texas A&M University, College Station, USA Contributor Haruta, Masatake, National Institute of Advanced Industrial Sci. & Tech., JAPA Contributor Hayden, Brian E., The Univ. of Southampton, Southampton, ENGLAND Contributor Henry, Claude R., CRMC2-CNRS, Marseille, FRANCE Contributor Illas, Francesc, Universitat de Barcelona, Barcelona, SPAIN Contributor Kasemo, B., Chalmers Univ. of Technology, Goteborg, SWEDEN Contributor Koel, Bruce E., University of Southern CA, LOS ANGELES, USA Contributor Koper, Marc T. M., Eindhoven Univ. of Technology, Eindhoven, THE NETHERLANDS Contributor Batzill, Matthias, University of Southern California, LOS ANGELES, USA Editor 1 Wieckowski, Andrzej, University of Illinois, Urbana, USA Editor 2 Savinova, Elena R., Russian Academy of Sciences, Novosibirsk Editor 3 Vayenas, Constantinos G., University of Patras, Greece |
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