One way to use engineered nanoparticles in the real world is in thin films. Such nanoparticulate films are thin layers, sometimes only a few nanometers thick, of composite materials that contain nanoparticles. These new materials have a wide range of applications in drug delivery, nanoelectronics, magnetic storage devices, sensors, or optical coating. However, most processes used to fabricate thin nanocomposite films with high nanoparticle fillings suffer from random nanoparticle agglomeration causing formation of irregularly shaped nanostructured features within the composite. Another complication arises from cracks that develop during the fabrication of the films. Researchers have now described a simple method for fabricating thick, crack-free silica nanoparticle films by subsequent deposition of thin, crack-free silica nanoparticle multilayers.